Photo Thermo Chemical Fuels
Photo Thermo Chemical Fuels are fuels that can be manufactured today using solar and thermal energy. There are a number of them:| Compound | Ingredients | Process | Economy? |
|---|---|---|---|
| Hydrogen | Water | Iron/Zinc/Nickel | Hydrolysis |
| Methanol | Hydrogen,CO2 | KOH Hydrolysis | More here |
| Ammonia | Hydrogen, N2 | Haber process | More here |
| Methane | Hydrogen,CO | Sabatier process | More here |
Which one is best?

source
I would advocate embracing only economies based on atmospheric capture of CO2 or no CO2 at all (Ammonia). Safety wise there is a clear winner : Ammonia. The risk associated with ammonia are about explosion of big tankers.
http://www.mpi.stonybrook.edu/energy/WaterSplitting/watersplitreview.pdf
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